PDE and mathematical physics · Oct 6, 2026

The ionization and generalized ionization conjectures

For the full nonrelativistic Coulomb model with two electron spin states, proves that a molecule with M fixed nuclei of charges at least one and total charge Z strictly binds at most Z+CMZ+CM electrons. Neutral-atom first ionization energies and radii containing all but an expected half-electron have universal positive upper and lower bounds. The energy cost of removing m electrons has Thomas–Fermi asymptotics as m→∞m\to\infty and Z/m→∞Z/m\to\infty; neutral-atom outer radii have the corresponding iterated-limit asymptotics, taking Z→∞Z\to\infty first.

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